New electrochemlcally generated polymeric pd complexes as heterogeneous catalysts for Suzuki cross-coupling reactions

Marco Bandini, Agostino Pietrangelo, Riccardo Sinisi, Achille Umani-Ronchi, Michael O. Wolf

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Electrochemically generated films of polymerized (diaminooligothiophene) palladium complexes as heterogeneous catalysts for Suzuki cross-coupling reactions are reported. The electrodeposition of these polymeric species onto porous graphite electrodes allows for easy removal of the organo-metallic species from the reaction mixture and convenient reuse in subsequent (up to 6) reactions.

Original languageEnglish (US)
Pages (from-to)3554-3561
Number of pages8
JournalEuropean Journal of Organic Chemistry
Issue number21
DOIs
StatePublished - Jul 2009

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry

Keywords

  • Cross-coupling
  • Electropolymerization
  • Heterogeneous catalysis
  • Palladium
  • Sulfur heterocycles

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