New fluorination of organic compounds using thermodynamically unstable nickel fluorides

Neil Bartlett, Richard D. Chambers, Alex J. Roche, Robert C.H. Spink, Lisa Chacón, J. Marc Whalen

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

Replacement of hydrogen by fluorine in a variety of organic compounds is accomplished with high efficiency in liquid hydrogen fluoride (aHF), at or below 20°C, using the thermodynamically unstable fluorides RNiF3 and NiF4, the latter prepared in situ from K2NiF6 with BF3.

Original languageEnglish (US)
Pages (from-to)1049-1050
Number of pages2
JournalChemical Communications
Issue number9
DOIs
StatePublished - 1996
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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