New Type of Polymeric Indium Tellurides: Low-Temperature Synthesis and Structure Characterization of [M(en)3]In2Te6 (M = Fe, Zn) and α- And β-[Mo3(en)3(μ2-Te2) 3(μ3-Te)(μ3-O)]In2Te 6

Jing Li; Zhen Chen; Thomas J. Emge; Davide M. Proserpio

doi:10.1021/ic960751v

New Type of Polymeric Indium Tellurides: Low-Temperature Synthesis and Structure Characterization of [M(en)₃]In₂Te₆ (M = Fe, Zn) and α- And β-[Mo₃(en)₃(μ₂-Te₂) ₃(μ₃-Te)(μ₃-O)]In₂Te ₆

Jing Li, Zhen Chen, Thomas J. Emge, Davide M. Proserpio

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in four new indium tellurium phases, [Fe(en)₃](In₂Te₆) (I), [Zn(en)₃](In₂Te₆) (II), and α-and β-[Mo₃(en)₃(μ₂-Te₂) ₃(μ₃-Te)(μ₃-O)]In₂Te ₆ (III-α and III-β). Single crystal X-ray diffraction analyses show that I and II are isostructural and belong to the orthorhombic crystal system, space group P2₁2₁2₁ (No. 19). Compound I: a = 11.654 (1) Å, b = 12.968(2) Å, c = 16.273(2) Å, Z = 4. Compound II: a = 11.662(2) Å, b = 12.948(2) Å, c = 16.285(1) Å, Z = 4. The two polymorphs III-α and III-β crystallize in the monoclinic system. Compound III-α: a = 11.815(2) Å, b = 21.769(3)Å, c = 14.498(4) Å, β = 95.43(2)°, Z = 4, space group P2_1/c (No. 14). Compound III-β a = 22.154(3) Å, b = 11.550(2)Å, c = 14.230(2) Å, β = 99.05(1)°, Z = 4, space group P2_1/a (No. 14). All four are Zintl compounds containing novel one-dimensional polymeric chains of ¹_∞[(In₂Te₆)^2-] that can be described as alternating fused five-membered rings [(In³⁺)₂(Te₂^2-)(Te^2-)], joined at the In atoms.

Original language	English (US)
Pages (from-to)	1437-1442
Number of pages	6
Journal	Inorganic Chemistry
Volume	36
Issue number	7
DOIs	https://doi.org/10.1021/ic960751v
State	Published - Mar 26 1997

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic960751v

Cite this

@article{fa46ff123ec246ea977275a8c4892dad,

title = "New Type of Polymeric Indium Tellurides: Low-Temperature Synthesis and Structure Characterization of [M(en)3]In2Te6 (M = Fe, Zn) and α- And β-[Mo3(en)3(μ2-Te2) 3(μ3-Te)(μ3-O)]In2Te 6",

abstract = "Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in four new indium tellurium phases, [Fe(en)3](In2Te6) (I), [Zn(en)3](In2Te6) (II), and α-and β-[Mo3(en)3(μ2-Te2) 3(μ3-Te)(μ3-O)]In2Te 6 (III-α and III-β). Single crystal X-ray diffraction analyses show that I and II are isostructural and belong to the orthorhombic crystal system, space group P212121 (No. 19). Compound I: a = 11.654 (1) {\AA}, b = 12.968(2) {\AA}, c = 16.273(2) {\AA}, Z = 4. Compound II: a = 11.662(2) {\AA}, b = 12.948(2) {\AA}, c = 16.285(1) {\AA}, Z = 4. The two polymorphs III-α and III-β crystallize in the monoclinic system. Compound III-α: a = 11.815(2) {\AA}, b = 21.769(3){\AA}, c = 14.498(4) {\AA}, β = 95.43(2)°, Z = 4, space group P21/c (No. 14). Compound III-β a = 22.154(3) {\AA}, b = 11.550(2){\AA}, c = 14.230(2) {\AA}, β = 99.05(1)°, Z = 4, space group P21/a (No. 14). All four are Zintl compounds containing novel one-dimensional polymeric chains of 1∞[(In2Te6)2-] that can be described as alternating fused five-membered rings [(In3+)2(Te22-)(Te2-)], joined at the In atoms.",

author = "Jing Li and Zhen Chen and Emge, {Thomas J.} and Proserpio, {Davide M.}",

year = "1997",

month = mar,

day = "26",

doi = "10.1021/ic960751v",

language = "English (US)",

volume = "36",

pages = "1437--1442",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "7",

}

New Type of Polymeric Indium Tellurides: Low-Temperature Synthesis and Structure Characterization of [M(en)₃]In₂Te₆ (M = Fe, Zn) and α- And β-[Mo₃(en)₃(μ₂-Te₂) ₃(μ₃-Te)(μ₃-O)]In₂Te ₆. / Li, Jing; Chen, Zhen; Emge, Thomas J. et al.
In: Inorganic Chemistry, Vol. 36, No. 7, 26.03.1997, p. 1437-1442.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - New Type of Polymeric Indium Tellurides

T2 - Low-Temperature Synthesis and Structure Characterization of [M(en)3]In2Te6 (M = Fe, Zn) and α- And β-[Mo3(en)3(μ2-Te2) 3(μ3-Te)(μ3-O)]In2Te 6

AU - Li, Jing

AU - Chen, Zhen

AU - Emge, Thomas J.

AU - Proserpio, Davide M.

PY - 1997/3/26

Y1 - 1997/3/26

N2 - Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in four new indium tellurium phases, [Fe(en)3](In2Te6) (I), [Zn(en)3](In2Te6) (II), and α-and β-[Mo3(en)3(μ2-Te2) 3(μ3-Te)(μ3-O)]In2Te 6 (III-α and III-β). Single crystal X-ray diffraction analyses show that I and II are isostructural and belong to the orthorhombic crystal system, space group P212121 (No. 19). Compound I: a = 11.654 (1) Å, b = 12.968(2) Å, c = 16.273(2) Å, Z = 4. Compound II: a = 11.662(2) Å, b = 12.948(2) Å, c = 16.285(1) Å, Z = 4. The two polymorphs III-α and III-β crystallize in the monoclinic system. Compound III-α: a = 11.815(2) Å, b = 21.769(3)Å, c = 14.498(4) Å, β = 95.43(2)°, Z = 4, space group P21/c (No. 14). Compound III-β a = 22.154(3) Å, b = 11.550(2)Å, c = 14.230(2) Å, β = 99.05(1)°, Z = 4, space group P21/a (No. 14). All four are Zintl compounds containing novel one-dimensional polymeric chains of 1∞[(In2Te6)2-] that can be described as alternating fused five-membered rings [(In3+)2(Te22-)(Te2-)], joined at the In atoms.

AB - Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200°C have resulted in four new indium tellurium phases, [Fe(en)3](In2Te6) (I), [Zn(en)3](In2Te6) (II), and α-and β-[Mo3(en)3(μ2-Te2) 3(μ3-Te)(μ3-O)]In2Te 6 (III-α and III-β). Single crystal X-ray diffraction analyses show that I and II are isostructural and belong to the orthorhombic crystal system, space group P212121 (No. 19). Compound I: a = 11.654 (1) Å, b = 12.968(2) Å, c = 16.273(2) Å, Z = 4. Compound II: a = 11.662(2) Å, b = 12.948(2) Å, c = 16.285(1) Å, Z = 4. The two polymorphs III-α and III-β crystallize in the monoclinic system. Compound III-α: a = 11.815(2) Å, b = 21.769(3)Å, c = 14.498(4) Å, β = 95.43(2)°, Z = 4, space group P21/c (No. 14). Compound III-β a = 22.154(3) Å, b = 11.550(2)Å, c = 14.230(2) Å, β = 99.05(1)°, Z = 4, space group P21/a (No. 14). All four are Zintl compounds containing novel one-dimensional polymeric chains of 1∞[(In2Te6)2-] that can be described as alternating fused five-membered rings [(In3+)2(Te22-)(Te2-)], joined at the In atoms.

UR - http://www.scopus.com/inward/record.url?scp=0000622298&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000622298&partnerID=8YFLogxK

U2 - 10.1021/ic960751v

DO - 10.1021/ic960751v

M3 - Article

AN - SCOPUS:0000622298

SN - 0020-1669

VL - 36

SP - 1437

EP - 1442

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

New Type of Polymeric Indium Tellurides: Low-Temperature Synthesis and Structure Characterization of [M(en)₃]In₂Te₆ (M = Fe, Zn) and α- And β-[Mo₃(en)₃(μ₂-Te₂) ₃(μ₃-Te)(μ₃-O)]In₂Te ₆

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this