o-carboranylcarbene. A largely localized divalent carbon intermediate

Richard S. Mutton, Heinz D. Roth, Sarangan Chari

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Triplet EPR spectra of o-carboranylcarbene and its 2-methyl derivative have been observed at 5 K in frozen solutions. The zero-field splitting parameters indicate little delocalization of the π spin density onto the carboranyl moiety, in contrast to the results observed for benzenoid aromatic moieties.

Original languageEnglish (US)
Pages (from-to)753-754
Number of pages2
JournalJournal of physical chemistry
Volume85
Issue number7
DOIs
StatePublished - 1981
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physical and Theoretical Chemistry

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