Observed phase transformations of oxalate-derived lead monoxide powder

M. J. Munson, Richard Riman

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Abstract

The purpose of this study is to elucidate the nature of the phase transformations of lead monoxide powder. Lead monoxide is prepared by calcination of a lead oxalate precursor salt, and its phase transformations are studied using X-ray diffraction (XRD), differential scanning calorimetry (DSC) and thermal gravimetric analysis (TG). Analysis reveals that the phase transformations observed for oxalate-derived lead monoxide powder are highly dependent on the firing atmosphere. In nitrogen, as the temperature is increased 1 deg/min from room temperature, lead monoxide undergoes a reconstructive litharge-to-massicot phase transformation in a temperature range of 525-575°C. In air, litharge, metastable at room temperature, slowly oxidizes to the Pb3O4 phase at a temperature of 350°C and rapidly reduces to litharge at 560°C. At temperatures greater than 560°C, litharge converts to massicot. With heating rates of 10 deg/min or higher, formation of Pb3O4 is not observed.

Original languageEnglish (US)
Pages (from-to)2555-2566
Number of pages12
JournalJournal of Thermal Analysis
Volume37
Issue number11-12
DOIs
Publication statusPublished - Nov 1 1991

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Engineering(all)

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