One-pot, 18-component synthesis of an octahedral nanocontainer molecule

Xuejun Liu; Yong Liu; Gina Li; Ralf Warmuth

doi:10.1002/anie.200504049

One-pot, 18-component synthesis of an octahedral nanocontainer molecule

Xuejun Liu, Yong Liu, Gina Li, Ralf Warmuth

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

192 Scopus citations

Abstract

A whole in one! The octahedral nanocontainer 3 composed of six cavitands 1 that are connected together by 12 diamino bridging units 2 through 24 imine bonds was synthesized in nearly quantitative yield in a one-pot reaction. Molecular mechanics calculations and NMR experiments suggest that this container has a diameter of 3.2 Å and an inner cavity volume of about 1700 Å³. (Figure Presented).

Original language	English (US)
Pages (from-to)	901-904
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	6
DOIs	https://doi.org/10.1002/anie.200504049
State	Published - Jan 30 2006

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

Cavitands
Host-guest systems
Multicomponent reactions
Supramolecular chemistry

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10.1002/anie.200504049

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abstract = "A whole in one! The octahedral nanocontainer 3 composed of six cavitands 1 that are connected together by 12 diamino bridging units 2 through 24 imine bonds was synthesized in nearly quantitative yield in a one-pot reaction. Molecular mechanics calculations and NMR experiments suggest that this container has a diameter of 3.2 {\AA} and an inner cavity volume of about 1700 {\AA}3. (Figure Presented).",

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KW - Host-guest systems

KW - Multicomponent reactions

KW - Supramolecular chemistry

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One-pot, 18-component synthesis of an octahedral nanocontainer molecule

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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