Pd-Catalyzed C-H Activation: Expanding the Portfolio of Metal-Catalyzed Functionalization of Unreactive C-H Bonds by Arene-Chromium π-Complexation

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Abstract

Switch it on: η6-arene-transition-metal complexes are significant intermediates in organic chemistry; however, their use in C-H functionalization remain largely unexplored. Recently, new methodologies for the Pd-catalyzed C-H activation of unreactive sp2 and sp3 bonds that rely on the efficient activation of arenes by π-complexation have been developed. These reactions significantly expand the toolbox of modern C-H activation methods.

Original languageEnglish (US)
Pages (from-to)1061-1063
Number of pages3
JournalChemCatChem
Volume7
Issue number7
DOIs
Publication statusPublished - Apr 7 2015

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Keywords

  • C-H activation
  • arylation
  • chromium
  • homogenous catalysis
  • palladium

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