Penta-carbon-yl{3-[(2S)-1-methyl-pyrrolidin-2-yl]pyridine}tungsten(0)

Martin O. Onani, Roger A. Lalancette, Naftali T. Muriithi, Eunice A. Nyawade, Boitumelo V. Kgarebe

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3 Scopus citations

Abstract

The title compound, [W(C10H14N2)(CO) 5], contains five carbonyl ligands and a nicotine ligand in an octa-hedral arrangement around the tungsten atom. The metal atom shows cis angles in the range 87.30 (16)-94.2 (2)°, and trans angles between 175.2 (2) and 178.1 (4)°. The W - CO bond trans to the pyridine N atom [1.987 (6) Å] is noticeably shorter than the others, which range between 2.036 (3) and 2.064 (3) Å, possibly due to the well-known trans effect. The distance between the W atom and the pyridine N atom is 2.278 (4) Å.

Original languageEnglish (US)
Pages (from-to)m480
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number4
DOIs
StatePublished - 2010

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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