Predissociation and collisional depopulation of the Cs2(E) state

Z. Wu; J. Huennekens

doi:10.1063/1.447411

Predissociation and collisional depopulation of the Cs₂(E) state

Z. Wu, J. Huennekens

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23 Scopus citations

Abstract

We report here an experimental study of depopulation mechanisms of the Cs₂(E) state. By combining ratios of atomic to molecular fluorescence with E state lifetimes obtained by the phase shift technique, all studied as a function of Cs density, we were able to obtain absolute values for predissociation, radiative, and collisional depopulation rates as well as the total quenching rates for the Cs₂(E) state. The results are discussed in relation to those of other experiments.

Original language	English (US)
Pages (from-to)	4433-4446
Number of pages	14
Journal	The Journal of Chemical Physics
Volume	81
Issue number	10
DOIs	https://doi.org/10.1063/1.447411
State	Published - 1984
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.447411

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title = "Predissociation and collisional depopulation of the Cs2(E) state",

abstract = "We report here an experimental study of depopulation mechanisms of the Cs2(E) state. By combining ratios of atomic to molecular fluorescence with E state lifetimes obtained by the phase shift technique, all studied as a function of Cs density, we were able to obtain absolute values for predissociation, radiative, and collisional depopulation rates as well as the total quenching rates for the Cs2(E) state. The results are discussed in relation to those of other experiments.",

author = "Z. Wu and J. Huennekens",

year = "1984",

doi = "10.1063/1.447411",

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TY - JOUR

T1 - Predissociation and collisional depopulation of the Cs2(E) state

AU - Wu, Z.

AU - Huennekens, J.

PY - 1984

Y1 - 1984

N2 - We report here an experimental study of depopulation mechanisms of the Cs2(E) state. By combining ratios of atomic to molecular fluorescence with E state lifetimes obtained by the phase shift technique, all studied as a function of Cs density, we were able to obtain absolute values for predissociation, radiative, and collisional depopulation rates as well as the total quenching rates for the Cs2(E) state. The results are discussed in relation to those of other experiments.

AB - We report here an experimental study of depopulation mechanisms of the Cs2(E) state. By combining ratios of atomic to molecular fluorescence with E state lifetimes obtained by the phase shift technique, all studied as a function of Cs density, we were able to obtain absolute values for predissociation, radiative, and collisional depopulation rates as well as the total quenching rates for the Cs2(E) state. The results are discussed in relation to those of other experiments.

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U2 - 10.1063/1.447411

DO - 10.1063/1.447411

M3 - Article

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 10

ER -

Predissociation and collisional depopulation of the Cs₂(E) state

Abstract

All Science Journal Classification (ASJC) codes

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