Preparation and transport properties of the substituted blue bronze (Rb1-xCsx)0.3MoO3

B. T. Collins, K. V. Ramanujachary, M. Greenblatt, J. V. Waszczak

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Abstract

Electrical and magnetic transport properties have been measured on single crystals of the molybdenum blue bronze alloy system (Rb1-xCsx)0.3MoO3 prepared by the temperature gradient flux technique. Although the properties of the blue bronze are retained, cesium substitution decreases both ρ{variant} (298 K) and the transition temperature observed at 180 K for Rb0.3MoO3. Solid-state studies indicate that the upper limit of Cs doping is approximately 45%. Attempts are made to correlate the effects of cesium substitution with the observed changes in the transport properties.

Original languageEnglish (US)
Pages (from-to)348-355
Number of pages8
JournalJournal of Solid State Chemistry
Volume77
Issue number2
DOIs
StatePublished - Dec 1988

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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