Pressure-induced intercalation and amorphization in the Spin-Peierls compound CuGeO3

A. Jayaraman, S. Y. Wang, L. C. Ming, S. W. Cheong

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

High pressure Raman scattering and optical microscopic studies on CuGeO3 have been carried out in the diamond cell at room temperature. A pressure-induced reversible transition presumably due to intercalation of alcohol is observed at 7 GPa with 4:1 methanol ethanol as pressure medium. In this transition the sample dimension along the b axis visibly decreases by about 20%, preserving the single crystal nature. Such behavior is rather unique and unusual. Further, a pressure-induced reversible amorphization transition occurs near 15 GPa. Intercalation with H2O is also indicated near 9 GPa with no change in the sample dimension.

Original languageEnglish (US)
Pages (from-to)2356-2359
Number of pages4
JournalPhysical review letters
Volume75
Issue number12
DOIs
StatePublished - 1995
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Physics and Astronomy

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