Abstract
High pressure Raman scattering and optical microscopic studies on CuGeO3 have been carried out in the diamond cell at room temperature. A pressure-induced reversible transition presumably due to intercalation of alcohol is observed at 7 GPa with 4:1 methanol ethanol as pressure medium. In this transition the sample dimension along the b axis visibly decreases by about 20%, preserving the single crystal nature. Such behavior is rather unique and unusual. Further, a pressure-induced reversible amorphization transition occurs near 15 GPa. Intercalation with H2O is also indicated near 9 GPa with no change in the sample dimension.
Original language | English (US) |
---|---|
Pages (from-to) | 2356-2359 |
Number of pages | 4 |
Journal | Physical review letters |
Volume | 75 |
Issue number | 12 |
DOIs | |
State | Published - 1995 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- General Physics and Astronomy