Rate acceleration through dispersion interactions: Effect of a hemicarcerand on the transition state of inner phase decompositions of diazirines

Ralf Warmuth; Jean Luc Kerdelhué; Sigifredo Sánchez Carrera; Kevin J. Langenwalter; Neil Brown

doi:10.1002/1521-3773(20020104)41:1<96::AID-ANIE96>3.0.CO;2-W

Rate acceleration through dispersion interactions: Effect of a hemicarcerand on the transition state of inner phase decompositions of diazirines

Ralf Warmuth, Jean Luc Kerdelhué, Sigifredo Sánchez Carrera, Kevin J. Langenwalter, Neil Brown

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Incarceration strongly increases the rate of the thermal decomposition of diazirine 1 to yield carbene 2. The increase of the inner phase rate is rationalized by a stabilization of the transition through dispersion interactions between the breaking C-N bonds and one of the highly polarizable arene rings of the surrounding host 3.

Original language	English (US)
Pages (from-to)	96-99
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	1
DOIs	https://doi.org/10.1002/1521-3773(20020104)41:1<96::AID-ANIE96>3.0.CO;2-W
State	Published - Jan 4 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

Dispersion interactions
Hemicarcerands
Host-guest systems
Molecular container
Transition states

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10.1002/1521-3773(20020104)41:1<96::AID-ANIE96>3.0.CO;2-W

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Warmuth, R., Kerdelhué, J. L., Sánchez Carrera, S., Langenwalter, K. J., & Brown, N. (2002). Rate acceleration through dispersion interactions: Effect of a hemicarcerand on the transition state of inner phase decompositions of diazirines. Angewandte Chemie - International Edition, 41(1), 96-99. https://doi.org/10.1002/1521-3773(20020104)41:1<96::AID-ANIE96>3.0.CO;2-W

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title = "Rate acceleration through dispersion interactions: Effect of a hemicarcerand on the transition state of inner phase decompositions of diazirines",

abstract = "Incarceration strongly increases the rate of the thermal decomposition of diazirine 1 to yield carbene 2. The increase of the inner phase rate is rationalized by a stabilization of the transition through dispersion interactions between the breaking C-N bonds and one of the highly polarizable arene rings of the surrounding host 3.",

keywords = "Dispersion interactions, Hemicarcerands, Host-guest systems, Molecular container, Transition states",

author = "Ralf Warmuth and Kerdelhu{\'e}, {Jean Luc} and {S{\'a}nchez Carrera}, Sigifredo and Langenwalter, {Kevin J.} and Neil Brown",

year = "2002",

month = jan,

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doi = "10.1002/1521-3773(20020104)41:1<96::AID-ANIE96>3.0.CO;2-W",

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Warmuth, R, Kerdelhué, JL, Sánchez Carrera, S, Langenwalter, KJ & Brown, N 2002, 'Rate acceleration through dispersion interactions: Effect of a hemicarcerand on the transition state of inner phase decompositions of diazirines', Angewandte Chemie - International Edition, vol. 41, no. 1, pp. 96-99. https://doi.org/10.1002/1521-3773(20020104)41:1<96::AID-ANIE96>3.0.CO;2-W

Rate acceleration through dispersion interactions: Effect of a hemicarcerand on the transition state of inner phase decompositions of diazirines. / Warmuth, Ralf; Kerdelhué, Jean Luc; Sánchez Carrera, Sigifredo et al.
In: Angewandte Chemie - International Edition, Vol. 41, No. 1, 04.01.2002, p. 96-99.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Rate acceleration through dispersion interactions

T2 - Effect of a hemicarcerand on the transition state of inner phase decompositions of diazirines

AU - Warmuth, Ralf

AU - Kerdelhué, Jean Luc

AU - Sánchez Carrera, Sigifredo

AU - Langenwalter, Kevin J.

AU - Brown, Neil

PY - 2002/1/4

Y1 - 2002/1/4

N2 - Incarceration strongly increases the rate of the thermal decomposition of diazirine 1 to yield carbene 2. The increase of the inner phase rate is rationalized by a stabilization of the transition through dispersion interactions between the breaking C-N bonds and one of the highly polarizable arene rings of the surrounding host 3.

AB - Incarceration strongly increases the rate of the thermal decomposition of diazirine 1 to yield carbene 2. The increase of the inner phase rate is rationalized by a stabilization of the transition through dispersion interactions between the breaking C-N bonds and one of the highly polarizable arene rings of the surrounding host 3.

KW - Dispersion interactions

KW - Hemicarcerands

KW - Host-guest systems

KW - Molecular container

KW - Transition states

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JF - Angewandte Chemie - International Edition

IS - 1

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Rate acceleration through dispersion interactions: Effect of a hemicarcerand on the transition state of inner phase decompositions of diazirines

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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