TY - JOUR
T1 - Regiodivergent addition of phenols to allylic oxides
T2 - Control of 1,2- and 1,4-additions for cyclitol synthesis
AU - Moschitto, Matthew J.
AU - Vaccarello, David N.
AU - Lewis, Chad A.
N1 - Publisher Copyright:
© 2015 Wiley-VCH Verlag GmbH & Co. KGaA.
PY - 2015/2/9
Y1 - 2015/2/9
N2 - Control of 1,2- and 1,4-addition of substituted phenols to allylic oxides is achieved by intercepting palladium π-allyl complexes. The interconversion of palladium complexes results in the total synthesis of MK7607, cyathiformine B type, streptol, and a new cyclitol.
AB - Control of 1,2- and 1,4-addition of substituted phenols to allylic oxides is achieved by intercepting palladium π-allyl complexes. The interconversion of palladium complexes results in the total synthesis of MK7607, cyathiformine B type, streptol, and a new cyclitol.
KW - Carbasugars
KW - Homogeneous catalysis
KW - Palladium
KW - Regiodivergence
KW - Synthetic methods
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U2 - 10.1002/anie.201410228
DO - 10.1002/anie.201410228
M3 - Article
C2 - 25533617
AN - SCOPUS:84922428560
SN - 1433-7851
VL - 54
SP - 2142
EP - 2145
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 7
ER -