@article{b2eb7008de5c4d1684fbc617b0122a3c,
title = "Rh-Catalyzed Base-Free Decarbonylative Borylation of Twisted Amides",
abstract = "We report the rhodium-catalyzed base-free decarbonylative borylation of twisted amides. The synthesis of versatile arylboronate esters from aryl twisted amides is achieved via decarbonylative rhodium(I) catalysis and highly selective N-C(O) insertion. The method is notable for a very practical, additive-free Rh(I) catalyst system. The method shows broad functional group tolerance and excellent substrate scope, including site-selective decarbonylative borylation/Heck cross-coupling via divergent N-C/C-Br cleavage and late-stage pharmaceutical borylation.",
author = "Fusheng Bie and Xuejing Liu and Yijun Shi and Han Cao and Ying Han and Michal Szostak and Chengwei Liu and Xuejing Liu and Michal Szostak and Chengwei Liu",
note = "Funding Information: We thank Zaozhuang University, Shandong Lunan Coal Chemical Research Institute of Engineering and Technology, Zaozhuang Science and Technology Development Program (No. 2018GH19), NSF (CAREER CHE-1650766) and Rutgers University for financial support. The Bruker 400 MHz spectrometer used in this study was supported by College of Chemistry, Chemical Engineering and Materials Science at Zaozhuang University Funding Information: We thank Zaozhuang University, Shandong Lunan Coal Chemical Research Institute of Engineering and Technology, Zaozhuang Science and Technology Development Program (No. 2018GH19), NSF (CAREER CHE-1650766) and Rutgers University for financial support. The Bruker 400 MHz spectrometer used in this study was supported by College of Chemistry, Chemical Engineering and Materials Science at Zaozhuang University. Publisher Copyright: {\textcopyright} ",
year = "2020",
month = dec,
day = "4",
doi = "10.1021/acs.joc.0c02157",
language = "English (US)",
volume = "85",
pages = "15676--15685",
journal = "Journal of Organic Chemistry",
issn = "0022-3263",
publisher = "American Chemical Society",
number = "23",
}