Robust and aligned carbon nanotube/titania core/shell films for flexible tco-free photoelectrodes

Jiangtao Di, Zhenzhong Yong, Zhaojun Yao, Xiangyang Liu, Xiaojuan Shen, Baoquan Sun, Zhigang Zhao, Huixin He, Qingwen Li

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

Carbon nanotube (CNT)/semiconducting oxide hybrids are an ideal architecture for light-harvesting devices, in which the CNTs are expected to not only act as a scaffold but also provide fast transport paths for photogenerated charges in the oxide. However, the current potential of CNTs for charge transport is largely suppressed due to the nanotubes not being interconnected but isolated by the low conductive oxide coatings. Herein, a flexible and conductive CNT/TiO2 core/shell heterostructure film is reported, with aligned and interconnected CNTs wrapped in a continuous TiO2 coating. Without using additional transparent conducting oxide (TCO) substrates, this unique feature of the film boosts the incident photon-to-electron conversion efficiency to 32%, outperforming TiO2 nanoparticle electrodes fabricated on TCO substrates. Moreover, the film shows high structural stability and can generate a stable photocurrent even after being bent hundreds of times. A flexible and conducting heterostructure film with aligned carbon nanotubes wrapped in a continuous TiO2 coating is reported. Enhanced photoconversion efficiency is observed in the film compared with TiO2 nanoparticle electrodes fabricated on transparent conducting oxide (TCO) films. The film shows high structural stability and can generate a stable photocurrent even after being bent hundreds of times.

Original languageEnglish (US)
Pages (from-to)148-155
Number of pages8
JournalSmall
Volume9
Issue number1
DOIs
StatePublished - Jan 14 2013

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Biomaterials
  • Chemistry(all)
  • Materials Science(all)

Keywords

  • carbon nanotubes
  • photoelectrochemical cells
  • solar cells
  • titanium dioxide
  • water splitting

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