Rutile phases in the CrNbO4VO2MoO2 system: Preparation and properties

C. J. Chen, Martha Greenblatt, K. Ravindran Nair, J. V. Waszczak

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A wide domain of solid solutions have been prepared in the CrNbO4VO2MoO2 system with rutile-type structure. Electrical conductivity (77-300 K) and magnetic susceptibility (4.2-300 K) measurements of the samples show small band gap semiconducting behavior with very low activation energies (Ea < kT) and strong magnetic interactions of the metal ions, respectively. The magnitude of electrical conductivity and magnetic interactions increases with increasing Mo content. The transport properties are discussed in terms of the structural and electronic properties of the compounds. Results of lithium insertion reactions on selected compounds are also presented.

Original languageEnglish (US)
Pages (from-to)81-89
Number of pages9
JournalJournal of Solid State Chemistry
Volume64
Issue number1
DOIs
StatePublished - Jan 1 1986

Fingerprint

rutile
preparation
electrical resistivity
Magnetic susceptibility
Lithium
Electronic properties
Transport properties
Metal ions
Structural properties
insertion
Solid solutions
metal ions
Energy gap
solid solutions
Activation energy
lithium
transport properties
interactions
activation energy
magnetic permeability

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Chen, C. J. ; Greenblatt, Martha ; Nair, K. Ravindran ; Waszczak, J. V. / Rutile phases in the CrNbO4VO2MoO2 system : Preparation and properties. In: Journal of Solid State Chemistry. 1986 ; Vol. 64, No. 1. pp. 81-89.
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Rutile phases in the CrNbO4VO2MoO2 system : Preparation and properties. / Chen, C. J.; Greenblatt, Martha; Nair, K. Ravindran; Waszczak, J. V.

In: Journal of Solid State Chemistry, Vol. 64, No. 1, 01.01.1986, p. 81-89.

Research output: Contribution to journalArticle

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T1 - Rutile phases in the CrNbO4VO2MoO2 system

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