Separation of hydrocarbons with a microporous metal-organic framework

Long Pan; David H. Olson; Lauren R. Ciemnolonski; Ryan Heady; Jing Li

doi:10.1002/anie.200503503

Separation of hydrocarbons with a microporous metal-organic framework

Long Pan, David H. Olson, Lauren R. Ciemnolonski, Ryan Heady, Jing Li

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

721 Scopus citations

Abstract

Separating the wheat from the chaff: The microporous metal-organic framework (MMOF) of [Cu(hfipbb)(H₂hfipbb)_0.5] is based on a bimetallic paddle-wheel building block and comprises 1D tubular microchannels formed by the interpenetration of two identical 4⁴ nets. The channels are hydrophobic and have the ideal size and shape to selectively adsorb C ₂, C₃, and n-C₄ olefins and alkanes (see picture). (Figure Presented)

Original language	English (US)
Pages (from-to)	616-619
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	4
DOIs	https://doi.org/10.1002/anie.200503503
State	Published - Jan 16 2006

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

Adsorption
Hydrocarbons
Hydrothermal synthesis
Microporous materials

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10.1002/anie.200503503

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T1 - Separation of hydrocarbons with a microporous metal-organic framework

AU - Pan, Long

AU - Olson, David H.

AU - Ciemnolonski, Lauren R.

AU - Heady, Ryan

AU - Li, Jing

PY - 2006/1/16

Y1 - 2006/1/16

N2 - Separating the wheat from the chaff: The microporous metal-organic framework (MMOF) of [Cu(hfipbb)(H2hfipbb)0.5] is based on a bimetallic paddle-wheel building block and comprises 1D tubular microchannels formed by the interpenetration of two identical 44 nets. The channels are hydrophobic and have the ideal size and shape to selectively adsorb C 2, C3, and n-C4 olefins and alkanes (see picture). (Figure Presented)

AB - Separating the wheat from the chaff: The microporous metal-organic framework (MMOF) of [Cu(hfipbb)(H2hfipbb)0.5] is based on a bimetallic paddle-wheel building block and comprises 1D tubular microchannels formed by the interpenetration of two identical 44 nets. The channels are hydrophobic and have the ideal size and shape to selectively adsorb C 2, C3, and n-C4 olefins and alkanes (see picture). (Figure Presented)

KW - Adsorption

KW - Hydrocarbons

KW - Hydrothermal synthesis

KW - Microporous materials

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Separation of hydrocarbons with a microporous metal-organic framework

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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