Solubility and diffusivity of solvents by packed column inverse gas chromatography

James V. Scicolone; Peter K. Davis; Ronald P. Danner; J. Larry Duda

doi:10.1016/j.polymer.2006.05.047

Solubility and diffusivity of solvents by packed column inverse gas chromatography

James V. Scicolone, Peter K. Davis, Ronald P. Danner, J. Larry Duda

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Inverse gas chromatography was used with solid polymer particles in packed columns to measure polymer-solvent solubility and diffusion. A new model for this IGC technique has been developed and used to obtain experimental results for n-pentane, isopentane, 1-hexene, n-hexane, and 1-octene solvents in polymer beads of polyethylene. The conditions were measured for solvents at infinite dilution, and experimental data were obtained for the binary polymer-solvent systems in a temperature range from 70 to 100 °C.

Original language	English (US)
Pages (from-to)	5364-5370
Number of pages	7
Journal	Polymer
Volume	47
Issue number	15
DOIs	https://doi.org/10.1016/j.polymer.2006.05.047
State	Published - Jul 12 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Materials Chemistry

Keywords

Diffusivity
Inverse gas chromatography
Solubility

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10.1016/j.polymer.2006.05.047

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title = "Solubility and diffusivity of solvents by packed column inverse gas chromatography",

abstract = "Inverse gas chromatography was used with solid polymer particles in packed columns to measure polymer-solvent solubility and diffusion. A new model for this IGC technique has been developed and used to obtain experimental results for n-pentane, isopentane, 1-hexene, n-hexane, and 1-octene solvents in polymer beads of polyethylene. The conditions were measured for solvents at infinite dilution, and experimental data were obtained for the binary polymer-solvent systems in a temperature range from 70 to 100 °C.",

keywords = "Diffusivity, Inverse gas chromatography, Solubility",

author = "Scicolone, {James V.} and Davis, {Peter K.} and Danner, {Ronald P.} and Duda, {J. Larry}",

year = "2006",

month = jul,

day = "12",

doi = "10.1016/j.polymer.2006.05.047",

language = "English (US)",

volume = "47",

pages = "5364--5370",

journal = "Polymer",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Solubility and diffusivity of solvents by packed column inverse gas chromatography

AU - Scicolone, James V.

AU - Davis, Peter K.

AU - Danner, Ronald P.

AU - Duda, J. Larry

PY - 2006/7/12

Y1 - 2006/7/12

N2 - Inverse gas chromatography was used with solid polymer particles in packed columns to measure polymer-solvent solubility and diffusion. A new model for this IGC technique has been developed and used to obtain experimental results for n-pentane, isopentane, 1-hexene, n-hexane, and 1-octene solvents in polymer beads of polyethylene. The conditions were measured for solvents at infinite dilution, and experimental data were obtained for the binary polymer-solvent systems in a temperature range from 70 to 100 °C.

AB - Inverse gas chromatography was used with solid polymer particles in packed columns to measure polymer-solvent solubility and diffusion. A new model for this IGC technique has been developed and used to obtain experimental results for n-pentane, isopentane, 1-hexene, n-hexane, and 1-octene solvents in polymer beads of polyethylene. The conditions were measured for solvents at infinite dilution, and experimental data were obtained for the binary polymer-solvent systems in a temperature range from 70 to 100 °C.

KW - Diffusivity

KW - Inverse gas chromatography

KW - Solubility

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U2 - 10.1016/j.polymer.2006.05.047

DO - 10.1016/j.polymer.2006.05.047

M3 - Article

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SN - 0032-3861

VL - 47

SP - 5364

EP - 5370

JO - Polymer

JF - Polymer

IS - 15

ER -

Solubility and diffusivity of solvents by packed column inverse gas chromatography

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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