Stereoisomers of Bicyclo[8.8.2]icos-19-ene: Synthesis, Novel Properties, and Molecular Mechanics Calculations

Roger S. Macomber; Daniel E. Rardon; Thomas J. Emge

doi:10.1021/jo00028a009

Stereoisomers of Bicyclo[8.8.2]icos-19-ene: Synthesis, Novel Properties, and Molecular Mechanics Calculations

Roger S. Macomber, Daniel E. Rardon, Thomas J. Emge

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A mixture comprising four of the five possible stereoisomers of title compound 1, novel bicyclic alkenes with properties resembling those of betweenanenes,² has been synthesized in four steps from 1,10-cyclooctadecadione (2).³ Molecular mechanics calculations have been performed on all five stereoisomers of 1.

Original language	English (US)
Pages (from-to)	433-434
Number of pages	2
Journal	Journal of Organic Chemistry
Volume	57
Issue number	2
DOIs	https://doi.org/10.1021/jo00028a009
State	Published - Jan 1 1992
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1021/jo00028a009

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title = "Stereoisomers of Bicyclo[8.8.2]icos-19-ene: Synthesis, Novel Properties, and Molecular Mechanics Calculations",

abstract = "A mixture comprising four of the five possible stereoisomers of title compound 1, novel bicyclic alkenes with properties resembling those of betweenanenes,2 has been synthesized in four steps from 1,10-cyclooctadecadione (2).3 Molecular mechanics calculations have been performed on all five stereoisomers of 1.",

author = "Macomber, {Roger S.} and Rardon, {Daniel E.} and Emge, {Thomas J.}",

year = "1992",

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doi = "10.1021/jo00028a009",

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journal = "Journal of Organic Chemistry",

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AU - Rardon, Daniel E.

AU - Emge, Thomas J.

PY - 1992/1/1

Y1 - 1992/1/1

N2 - A mixture comprising four of the five possible stereoisomers of title compound 1, novel bicyclic alkenes with properties resembling those of betweenanenes,2 has been synthesized in four steps from 1,10-cyclooctadecadione (2).3 Molecular mechanics calculations have been performed on all five stereoisomers of 1.

AB - A mixture comprising four of the five possible stereoisomers of title compound 1, novel bicyclic alkenes with properties resembling those of betweenanenes,2 has been synthesized in four steps from 1,10-cyclooctadecadione (2).3 Molecular mechanics calculations have been performed on all five stereoisomers of 1.

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Stereoisomers of Bicyclo[8.8.2]icos-19-ene: Synthesis, Novel Properties, and Molecular Mechanics Calculations

Abstract

All Science Journal Classification (ASJC) codes

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