Stereospecific cyclopropane ring-openign via one-electron oxidation of organo-iron complexes; crystal structure of [Fe2(CO)6(η4,η'4-C16H18)]

Neil G. Connelly; Andrew R. Lucy; Rona M. Mills; John B. Sheridan; Mark W. Whiteley; Peter Woodward

doi:10.1039/C39820001057

Stereospecific cyclopropane ring-openign via one-electron oxidation of organo-iron complexes; crystal structure of [Fe₂(CO)₆(η⁴,η^'4-C₁₆H₁₈)]

Neil G. Connelly, Andrew R. Lucy, Rona M. Mills, John B. Sheridan, Mark W. Whiteley, Peter Woodward

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The oxidation of [Fe₂(CO)₆(η⁴,η'⁴-C₁₆H₁₈)] and of [Fe₂(CO)₆(η⁴,η'⁴-C₁₆H₁₈)] ieads to stereospecific cyclopropane ring-opening and the isolation of (4) and (5) with exocyclic trans-and cis-double bonds, respectively; (5) is reduced to (6) with cyclobutane ring formation.

Original language	English (US)
Pages (from-to)	1057-1059
Number of pages	3
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C39820001057
State	Published - 1982
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39820001057

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title = "Stereospecific cyclopropane ring-openign via one-electron oxidation of organo-iron complexes; crystal structure of [Fe2(CO)6(η4,η'4-C16H18)]",

abstract = "The oxidation of [Fe2(CO)6(η4,η'4-C16H18)] and of [Fe2(CO)6(η4,η'4-C16H18)] ieads to stereospecific cyclopropane ring-opening and the isolation of (4) and (5) with exocyclic trans-and cis-double bonds, respectively; (5) is reduced to (6) with cyclobutane ring formation.",

author = "Connelly, {Neil G.} and Lucy, {Andrew R.} and Mills, {Rona M.} and Sheridan, {John B.} and Whiteley, {Mark W.} and Peter Woodward",

year = "1982",

doi = "10.1039/C39820001057",

language = "English (US)",

pages = "1057--1059",

journal = "Journal of the Chemical Society - Series Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "18",

}

TY - JOUR

T1 - Stereospecific cyclopropane ring-openign via one-electron oxidation of organo-iron complexes; crystal structure of [Fe2(CO)6(η4,η'4-C16H18)]

AU - Connelly, Neil G.

AU - Lucy, Andrew R.

AU - Mills, Rona M.

AU - Sheridan, John B.

AU - Whiteley, Mark W.

AU - Woodward, Peter

PY - 1982

Y1 - 1982

N2 - The oxidation of [Fe2(CO)6(η4,η'4-C16H18)] and of [Fe2(CO)6(η4,η'4-C16H18)] ieads to stereospecific cyclopropane ring-opening and the isolation of (4) and (5) with exocyclic trans-and cis-double bonds, respectively; (5) is reduced to (6) with cyclobutane ring formation.

AB - The oxidation of [Fe2(CO)6(η4,η'4-C16H18)] and of [Fe2(CO)6(η4,η'4-C16H18)] ieads to stereospecific cyclopropane ring-opening and the isolation of (4) and (5) with exocyclic trans-and cis-double bonds, respectively; (5) is reduced to (6) with cyclobutane ring formation.

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U2 - 10.1039/C39820001057

DO - 10.1039/C39820001057

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EP - 1059

JO - Journal of the Chemical Society - Series Chemical Communications

JF - Journal of the Chemical Society - Series Chemical Communications

IS - 18

ER -

Stereospecific cyclopropane ring-openign via one-electron oxidation of organo-iron complexes; crystal structure of [Fe₂(CO)₆(η⁴,η^'4-C₁₆H₁₈)]

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