Steric and electronic tuning of Cu(I) phenanthroline complexes for solar energy conversion

Nosheen Akber Gothard; Michael W. Mara; Jodi Szarko; Jenny V. Lockard; Sonbinh T. Nguyen; Lin X. Chen

Steric and electronic tuning of Cu(I) phenanthroline complexes for solar energy conversion

Nosheen Akber Gothard
, Michael W. Mara
, Jodi Szarko
, Jenny V. Lockard
, Sonbinh T. Nguyen
, Lin X. Chen

Research output: Contribution to journal › Conference article › peer-review

Abstract

Copper(I) phenanthroline complexes have very similar optical properties as quintessential Ru(II)polypyridyl complexes that are used extensively in dye-sensitized solar cells. To investigate this application, a set of homologous copper(I) phenanthroline complexes (1-6) have been prepared, where structural factors, such as the resistance of the Jahn-Teller distortion from Cu(I) to Cu(II)* can be systematically altered. We will present these results as well as a correlation of the ground and excited state structural dynamics of (2,9-di-tert-butyl-1,10-phenanthroline) copper(I) [Cu^I(dtbp)₂] through ultrafast optical studies.

Original language	English (US)
Journal	ACS National Meeting Book of Abstracts
State	Published - 2011
Externally published	Yes
Event	241st ACS National Meeting and Exposition - Anaheim, CA, United States Duration: Mar 27 2011 → Mar 31 2011

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

Cite this

@article{7ba828575a8648c8a1961dc5591946c7,

title = "Steric and electronic tuning of Cu(I) phenanthroline complexes for solar energy conversion",

abstract = "Copper(I) phenanthroline complexes have very similar optical properties as quintessential Ru(II)polypyridyl complexes that are used extensively in dye-sensitized solar cells. To investigate this application, a set of homologous copper(I) phenanthroline complexes (1-6) have been prepared, where structural factors, such as the resistance of the Jahn-Teller distortion from Cu(I) to Cu(II)* can be systematically altered. We will present these results as well as a correlation of the ground and excited state structural dynamics of (2,9-di-tert-butyl-1,10-phenanthroline) copper(I) [CuI(dtbp)2] through ultrafast optical studies.",

author = "\{Akber Gothard\}, Nosheen and Mara, \{Michael W.\} and Jodi Szarko and Lockard, \{Jenny V.\} and Nguyen, \{Sonbinh T.\} and Chen, \{Lin X.\}",

year = "2011",

language = "English (US)",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

note = "241st ACS National Meeting and Exposition ; Conference date: 27-03-2011 Through 31-03-2011",

}

TY - JOUR

T1 - Steric and electronic tuning of Cu(I) phenanthroline complexes for solar energy conversion

AU - Akber Gothard, Nosheen

AU - Mara, Michael W.

AU - Szarko, Jodi

AU - Lockard, Jenny V.

AU - Nguyen, Sonbinh T.

AU - Chen, Lin X.

PY - 2011

Y1 - 2011

N2 - Copper(I) phenanthroline complexes have very similar optical properties as quintessential Ru(II)polypyridyl complexes that are used extensively in dye-sensitized solar cells. To investigate this application, a set of homologous copper(I) phenanthroline complexes (1-6) have been prepared, where structural factors, such as the resistance of the Jahn-Teller distortion from Cu(I) to Cu(II)* can be systematically altered. We will present these results as well as a correlation of the ground and excited state structural dynamics of (2,9-di-tert-butyl-1,10-phenanthroline) copper(I) [CuI(dtbp)2] through ultrafast optical studies.

AB - Copper(I) phenanthroline complexes have very similar optical properties as quintessential Ru(II)polypyridyl complexes that are used extensively in dye-sensitized solar cells. To investigate this application, a set of homologous copper(I) phenanthroline complexes (1-6) have been prepared, where structural factors, such as the resistance of the Jahn-Teller distortion from Cu(I) to Cu(II)* can be systematically altered. We will present these results as well as a correlation of the ground and excited state structural dynamics of (2,9-di-tert-butyl-1,10-phenanthroline) copper(I) [CuI(dtbp)2] through ultrafast optical studies.

UR - https://www.scopus.com/pages/publications/80051910756

UR - https://www.scopus.com/pages/publications/80051910756#tab=citedBy

M3 - Conference article

AN - SCOPUS:80051910756

SN - 0065-7727

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

T2 - 241st ACS National Meeting and Exposition

Y2 - 27 March 2011 through 31 March 2011

ER -

Steric and electronic tuning of Cu(I) phenanthroline complexes for solar energy conversion

Abstract

All Science Journal Classification (ASJC) codes

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