Abstract
Above pH 12, a single ultrasonic relaxation absorption was observed at 100 MHz, while two relaxational frequencies were observed near pH 7 in 5′-GMP aqueous solutions. The single relaxation observed above pH 12 was attributed to a perturbation of the syn-anti rotational isomerization around the glycosyl bond based on the concentration and pH dependence of the relaxation frequency and the maximum absorption per wavelength. The kinetic and thermodynamic parameters were determined for the isomerization reaction. The results for the isomerization around the glycosyl bond in 5′-GMP are compared to those reported on related systems, and from such a comparison the effects of structural changes on the dynamics of syn-anti isomerization can be deduced.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1391-1394 |
| Number of pages | 4 |
| Journal | Journal of Physical Chemistry B |
| Volume | 104 |
| Issue number | 6 |
| State | Published - Feb 17 2000 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Surfaces, Coatings and Films
- Materials Chemistry
Cite this
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Structural effect of nucleotides on syn-anti glycosyl isomerization kinetics by ultrasonic relaxation methods. / Nishikawa, Sadakatsu; Huang, Hua; Jordan, Frank.
In: Journal of Physical Chemistry B, Vol. 104, No. 6, 17.02.2000, p. 1391-1394.Research output: Contribution to journal › Article
TY - JOUR
T1 - Structural effect of nucleotides on syn-anti glycosyl isomerization kinetics by ultrasonic relaxation methods
AU - Nishikawa, Sadakatsu
AU - Huang, Hua
AU - Jordan, Frank
PY - 2000/2/17
Y1 - 2000/2/17
N2 - Above pH 12, a single ultrasonic relaxation absorption was observed at 100 MHz, while two relaxational frequencies were observed near pH 7 in 5′-GMP aqueous solutions. The single relaxation observed above pH 12 was attributed to a perturbation of the syn-anti rotational isomerization around the glycosyl bond based on the concentration and pH dependence of the relaxation frequency and the maximum absorption per wavelength. The kinetic and thermodynamic parameters were determined for the isomerization reaction. The results for the isomerization around the glycosyl bond in 5′-GMP are compared to those reported on related systems, and from such a comparison the effects of structural changes on the dynamics of syn-anti isomerization can be deduced.
AB - Above pH 12, a single ultrasonic relaxation absorption was observed at 100 MHz, while two relaxational frequencies were observed near pH 7 in 5′-GMP aqueous solutions. The single relaxation observed above pH 12 was attributed to a perturbation of the syn-anti rotational isomerization around the glycosyl bond based on the concentration and pH dependence of the relaxation frequency and the maximum absorption per wavelength. The kinetic and thermodynamic parameters were determined for the isomerization reaction. The results for the isomerization around the glycosyl bond in 5′-GMP are compared to those reported on related systems, and from such a comparison the effects of structural changes on the dynamics of syn-anti isomerization can be deduced.
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M3 - Article
AN - SCOPUS:0008667455
VL - 104
SP - 1391
EP - 1394
JO - Journal of Physical Chemistry B
JF - Journal of Physical Chemistry B
SN - 1520-6106
IS - 6
ER -