Structural study of NiO2 and CoO2 as end members of the lithiated compounds by in situ high resolution X-ray powder diffraction

L. Seguin; G. Amatucci; M. Anne; Y. Chabre; P. Strobel; J. M. Tarascon; G. Vaughan

doi:10.1016/S0378-7753(99)00110-X

Structural study of NiO₂ and CoO₂ as end members of the lithiated compounds by in situ high resolution X-ray powder diffraction

L. Seguin, G. Amatucci, M. Anne, Y. Chabre, P. Strobel, J. M. Tarascon, G. Vaughan

Inst Adv Material Dev&Nanotech

Research output: Contribution to journal › Conference article › peer-review

34 Scopus citations

Abstract

In-situ X-ray diffraction has been carried out on Li_xNiO₂ and Li_xCoO₂ batteries, using the high resolution powder diffractometer BM16 at ESRF (Grenoble, France). Diffraction was performed in transmission geometry through 1-mm thick Bellcore-type plastic batteries. The batteries were controlled in potentiostatic mode. During these experiments, end-members NiO₂ and CoO₂ have been isolated, and high resolution patterns have been recorded in order to solve their structures from powder data. NiO₂ structure is of CdI₂ type, with a monoclinic distortion. CoO₂ seems to be of CdCl₂ type also with a monoclinic distortion.

Original language	English (US)
Pages (from-to)	604-606
Number of pages	3
Journal	Journal of Power Sources
Volume	81-82
DOIs	https://doi.org/10.1016/S0378-7753(99)00110-X
State	Published - Sep 1999
Event	Proceedings of the 1998 Ninth International Meeting on Lithium Batteries - Edingburgh, United Kingdom Duration: Jul 12 1998 → Jul 17 1998

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

Keywords

Cobalt oxide
Nickel oxide
Structure resolution

Access to Document

10.1016/S0378-7753(99)00110-X

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@article{7ef4d8ebaf6d4b3b99dc86cf860e9cdf,

title = "Structural study of NiO2 and CoO2 as end members of the lithiated compounds by in situ high resolution X-ray powder diffraction",

abstract = "In-situ X-ray diffraction has been carried out on LixNiO2 and LixCoO2 batteries, using the high resolution powder diffractometer BM16 at ESRF (Grenoble, France). Diffraction was performed in transmission geometry through 1-mm thick Bellcore-type plastic batteries. The batteries were controlled in potentiostatic mode. During these experiments, end-members NiO2 and CoO2 have been isolated, and high resolution patterns have been recorded in order to solve their structures from powder data. NiO2 structure is of CdI2 type, with a monoclinic distortion. CoO2 seems to be of CdCl2 type also with a monoclinic distortion.",

keywords = "Cobalt oxide, Nickel oxide, Structure resolution",

author = "L. Seguin and G. Amatucci and M. Anne and Y. Chabre and P. Strobel and Tarascon, {J. M.} and G. Vaughan",

year = "1999",

month = sep,

doi = "10.1016/S0378-7753(99)00110-X",

language = "English (US)",

volume = "81-82",

pages = "604--606",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier",

note = "Proceedings of the 1998 Ninth International Meeting on Lithium Batteries ; Conference date: 12-07-1998 Through 17-07-1998",

}

TY - JOUR

T1 - Structural study of NiO2 and CoO2 as end members of the lithiated compounds by in situ high resolution X-ray powder diffraction

AU - Seguin, L.

AU - Amatucci, G.

AU - Anne, M.

AU - Chabre, Y.

AU - Strobel, P.

AU - Tarascon, J. M.

AU - Vaughan, G.

PY - 1999/9

Y1 - 1999/9

N2 - In-situ X-ray diffraction has been carried out on LixNiO2 and LixCoO2 batteries, using the high resolution powder diffractometer BM16 at ESRF (Grenoble, France). Diffraction was performed in transmission geometry through 1-mm thick Bellcore-type plastic batteries. The batteries were controlled in potentiostatic mode. During these experiments, end-members NiO2 and CoO2 have been isolated, and high resolution patterns have been recorded in order to solve their structures from powder data. NiO2 structure is of CdI2 type, with a monoclinic distortion. CoO2 seems to be of CdCl2 type also with a monoclinic distortion.

AB - In-situ X-ray diffraction has been carried out on LixNiO2 and LixCoO2 batteries, using the high resolution powder diffractometer BM16 at ESRF (Grenoble, France). Diffraction was performed in transmission geometry through 1-mm thick Bellcore-type plastic batteries. The batteries were controlled in potentiostatic mode. During these experiments, end-members NiO2 and CoO2 have been isolated, and high resolution patterns have been recorded in order to solve their structures from powder data. NiO2 structure is of CdI2 type, with a monoclinic distortion. CoO2 seems to be of CdCl2 type also with a monoclinic distortion.

KW - Cobalt oxide

KW - Nickel oxide

KW - Structure resolution

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U2 - 10.1016/S0378-7753(99)00110-X

DO - 10.1016/S0378-7753(99)00110-X

M3 - Conference article

AN - SCOPUS:0033185138

VL - 81-82

SP - 604

EP - 606

JO - Journal of Power Sources

JF - Journal of Power Sources

SN - 0378-7753

T2 - Proceedings of the 1998 Ninth International Meeting on Lithium Batteries

Y2 - 12 July 1998 through 17 July 1998

ER -