Sub-monolayer nucleation and growth of complex oxides at high supersaturation and rapid flux modulation

M. Kareev, S. Prosandeev, B. Gray, Jian Liu, P. Ryan, A. Kareev, Eun Ju Moon, Jak Chakhalian

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

We report on the unusual nanoscale kinetics of the layer-by-layer deposition of complex oxide heterostructures composed of a unit-cell thick correlated metal LaNiO3 and dielectric LaAlO3. The ultrathin multilayers demonstrate extremely good crystallinity and surface morphology maintained over the large number of layers, as confirmed by combination of AFM, RHEED, and synchrotron x-ray diffraction. To elucidate the physics behind the growth, the temperature of the substrate and the deposition rate are varied over a wide range and the results are treated in the framework of a two-layer model. The results demonstrate that, in addition to temperature and vapor supersaturation, modulated flux can be employed as a powerful kinetic handle for the fine-tuned manipulation of sub-monolayer growth regimes of multicomponent materials.

Original languageEnglish (US)
Article number114303
JournalJournal of Applied Physics
Volume109
Issue number11
DOIs
StatePublished - Jun 1 2011

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supersaturation
nucleation
modulation
oxides
kinetics
manipulators
crystallinity
synchrotrons
x ray diffraction
atomic force microscopy
vapors
physics
temperature
cells
metals

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Cite this

Kareev, M. ; Prosandeev, S. ; Gray, B. ; Liu, Jian ; Ryan, P. ; Kareev, A. ; Ju Moon, Eun ; Chakhalian, Jak. / Sub-monolayer nucleation and growth of complex oxides at high supersaturation and rapid flux modulation. In: Journal of Applied Physics. 2011 ; Vol. 109, No. 11.
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Sub-monolayer nucleation and growth of complex oxides at high supersaturation and rapid flux modulation. / Kareev, M.; Prosandeev, S.; Gray, B.; Liu, Jian; Ryan, P.; Kareev, A.; Ju Moon, Eun; Chakhalian, Jak.

In: Journal of Applied Physics, Vol. 109, No. 11, 114303, 01.06.2011.

Research output: Contribution to journalArticle

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AU - Kareev, M.

AU - Prosandeev, S.

AU - Gray, B.

AU - Liu, Jian

AU - Ryan, P.

AU - Kareev, A.

AU - Ju Moon, Eun

AU - Chakhalian, Jak

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