Synthesis and characterization of NiO-YSZ anode materials: Precipitation, calcination, and the effects on sintering

Catherine M. Grgicak, Richard G. Green, Wei Fang Du, Javier B. Giorgi

Research output: Contribution to journalArticlepeer-review

39 Scopus citations

Abstract

Nickel oxide yttria-stabilized zirconia (NiO-YSZ) anode materials were synthesized via hydrolysis of the corresponding chloride solutions with NH3, NH3+NaOH, and NaOH as precipitation agents. Powder properties such as crystallite size, morphology, and sintering behavior of the final NiO-YSZ materials were also studied. The mechanism of the formation of NiO-YSZ was established for the different co-precipitation techniques by the direct observation of Ni(NH3)n+2 complexes, Ni(OH)2 and NiO at different stages of the synthesis process. A direct relationship between the precipitation agent, the order of calcination from dry sample to final product, the final composition, the crystallite sizes and particle sizes of NiO, and the sinterability of the final products was established. A comparison of the powder and individual component properties indicate that the choice of precipitation agent greatly influences the final characteristics. NiYSZ materials prepared by NH3+NaOH precipitation offer higher Ni dispersion and nanocrystallinity of both the Ni and YSZ phases. The conductivity of both prepared materials compares well with mixed-oxide materials of higher Ni content.

Original languageEnglish (US)
Pages (from-to)3081-3087
Number of pages7
JournalJournal of the American Ceramic Society
Volume88
Issue number11
DOIs
StatePublished - Nov 1 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

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