Synthesis and structure of a hypercoordinate silicon-bridged [1]ferrocenophane

Frieder Jakle; Emira Vejzovic; K. Nicole Power-Billard; Mark J. MacLachlan; Alan J. Lough; Ian Manners

doi:10.1021/om000316f

Synthesis and structure of a hypercoordinate silicon-bridged [1]ferrocenophane

Frieder Jakle, Emira Vejzovic, K. Nicole Power-Billard, Mark J. MacLachlan, Alan J. Lough, Ian Manners

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The pentacoordination at the bridging silicon atom leads to dramatic structural changes for silicon-bridged [1]ferrocenophane in the solid state. The first hypercoordinate silicon-bridged [1]-ferrocenophane shows a pronounced Si-N interaction, a pseudo-trigonal-bipyramidal geometry at the bridging silicon atom, an elongated Si-Cp bond trans to the amino group, and an unusually long Fe-Si distance in comparison to the tetracoordinate analogues.

Original language	English (US)
Pages (from-to)	2826-2828
Number of pages	3
Journal	Organometallics
Volume	19
Issue number	15
DOIs	https://doi.org/10.1021/om000316f
State	Published - Jul 2000
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om000316f

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abstract = "The pentacoordination at the bridging silicon atom leads to dramatic structural changes for silicon-bridged [1]ferrocenophane in the solid state. The first hypercoordinate silicon-bridged [1]-ferrocenophane shows a pronounced Si-N interaction, a pseudo-trigonal-bipyramidal geometry at the bridging silicon atom, an elongated Si-Cp bond trans to the amino group, and an unusually long Fe-Si distance in comparison to the tetracoordinate analogues.",

author = "Frieder Jakle and Emira Vejzovic and Power-Billard, {K. Nicole} and MacLachlan, {Mark J.} and Lough, {Alan J.} and Ian Manners",

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AU - Jakle, Frieder

AU - Vejzovic, Emira

AU - Power-Billard, K. Nicole

AU - MacLachlan, Mark J.

AU - Lough, Alan J.

AU - Manners, Ian

PY - 2000/7

Y1 - 2000/7

N2 - The pentacoordination at the bridging silicon atom leads to dramatic structural changes for silicon-bridged [1]ferrocenophane in the solid state. The first hypercoordinate silicon-bridged [1]-ferrocenophane shows a pronounced Si-N interaction, a pseudo-trigonal-bipyramidal geometry at the bridging silicon atom, an elongated Si-Cp bond trans to the amino group, and an unusually long Fe-Si distance in comparison to the tetracoordinate analogues.

AB - The pentacoordination at the bridging silicon atom leads to dramatic structural changes for silicon-bridged [1]ferrocenophane in the solid state. The first hypercoordinate silicon-bridged [1]-ferrocenophane shows a pronounced Si-N interaction, a pseudo-trigonal-bipyramidal geometry at the bridging silicon atom, an elongated Si-Cp bond trans to the amino group, and an unusually long Fe-Si distance in comparison to the tetracoordinate analogues.

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JO - Organometallics

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Synthesis and structure of a hypercoordinate silicon-bridged [1]ferrocenophane

Abstract

All Science Journal Classification (ASJC) codes

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