The electron transfer induced interconversion of cyclobutanes and diolefins

Heinz D. Roth; Marcia L.M. Schilling; Toshio Mukai; Tsutomu Miyashi

doi:10.1016/S0040-4039(00)94209-6

The electron transfer induced interconversion of cyclobutanes and diolefins

Heinz D. Roth, Marcia L.M. Schilling, Toshio Mukai, Tsutomu Miyashi

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The photoreactions of quinones with diolefins (1) or cage compounds (2) give rise to nuclear spin polarization predominantly for the dilefins. These findings indicate that the cage cations (4) have shallow energy minima and suffer fast ring opening to the diolefin cations (3).

Original language	English (US)
Pages (from-to)	5815-5818
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	52
DOIs	https://doi.org/10.1016/S0040-4039(00)94209-6
State	Published - 1983
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)94209-6

Cite this

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title = "The electron transfer induced interconversion of cyclobutanes and diolefins",

abstract = "The photoreactions of quinones with diolefins (1) or cage compounds (2) give rise to nuclear spin polarization predominantly for the dilefins. These findings indicate that the cage cations (4) have shallow energy minima and suffer fast ring opening to the diolefin cations (3).",

author = "Roth, {Heinz D.} and Schilling, {Marcia L.M.} and Toshio Mukai and Tsutomu Miyashi",

year = "1983",

doi = "10.1016/S0040-4039(00)94209-6",

language = "English (US)",

volume = "24",

pages = "5815--5818",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "52",

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T1 - The electron transfer induced interconversion of cyclobutanes and diolefins

AU - Roth, Heinz D.

AU - Schilling, Marcia L.M.

AU - Mukai, Toshio

AU - Miyashi, Tsutomu

PY - 1983

Y1 - 1983

N2 - The photoreactions of quinones with diolefins (1) or cage compounds (2) give rise to nuclear spin polarization predominantly for the dilefins. These findings indicate that the cage cations (4) have shallow energy minima and suffer fast ring opening to the diolefin cations (3).

AB - The photoreactions of quinones with diolefins (1) or cage compounds (2) give rise to nuclear spin polarization predominantly for the dilefins. These findings indicate that the cage cations (4) have shallow energy minima and suffer fast ring opening to the diolefin cations (3).

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U2 - 10.1016/S0040-4039(00)94209-6

DO - 10.1016/S0040-4039(00)94209-6

M3 - Article

AN - SCOPUS:33646506206

SN - 0040-4039

VL - 24

SP - 5815

EP - 5818

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 52

ER -

The electron transfer induced interconversion of cyclobutanes and diolefins

Abstract

All Science Journal Classification (ASJC) codes

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