Transient innermolecular carbene-hemicarcerand complex of fluorophenylcarbene

Zhifeng Lu; Robert A. Moss; Ralf Warmuth; Karsten Krogh-Jespersen

doi:10.1021/jp2087785

Transient innermolecular carbene-hemicarcerand complex of fluorophenylcarbene

Zhifeng Lu, Robert A. Moss, Ralf Warmuth, Karsten Krogh-Jespersen

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Laser flash photolysis of fluorophenyldiazirine incarcerated in hemicarcerand 2 affords incarcerated fluorophenylcarbene [23], which forms a metastable, innermolecular π-complex with aryl moieties of 2. This carbene complex can be observed spectroscopically. Extensive computational studies provide insights into the structure, spectroscopy, energetics, and kinetics of the 23 carbene complex.

Original language	English (US)
Pages (from-to)	13799-13803
Number of pages	5
Journal	Journal of Physical Chemistry A
Volume	115
Issue number	47
DOIs	https://doi.org/10.1021/jp2087785
State	Published - Dec 1 2011

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry

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10.1021/jp2087785

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title = "Transient innermolecular carbene-hemicarcerand complex of fluorophenylcarbene",

abstract = "Laser flash photolysis of fluorophenyldiazirine incarcerated in hemicarcerand 2 affords incarcerated fluorophenylcarbene [23], which forms a metastable, innermolecular π-complex with aryl moieties of 2. This carbene complex can be observed spectroscopically. Extensive computational studies provide insights into the structure, spectroscopy, energetics, and kinetics of the 23 carbene complex.",

author = "Zhifeng Lu and Moss, {Robert A.} and Ralf Warmuth and Karsten Krogh-Jespersen",

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AU - Moss, Robert A.

AU - Warmuth, Ralf

AU - Krogh-Jespersen, Karsten

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N2 - Laser flash photolysis of fluorophenyldiazirine incarcerated in hemicarcerand 2 affords incarcerated fluorophenylcarbene [23], which forms a metastable, innermolecular π-complex with aryl moieties of 2. This carbene complex can be observed spectroscopically. Extensive computational studies provide insights into the structure, spectroscopy, energetics, and kinetics of the 23 carbene complex.

AB - Laser flash photolysis of fluorophenyldiazirine incarcerated in hemicarcerand 2 affords incarcerated fluorophenylcarbene [23], which forms a metastable, innermolecular π-complex with aryl moieties of 2. This carbene complex can be observed spectroscopically. Extensive computational studies provide insights into the structure, spectroscopy, energetics, and kinetics of the 23 carbene complex.

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Transient innermolecular carbene-hemicarcerand complex of fluorophenylcarbene

Abstract

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