Transient innermolecular carbene-hemicarcerand complex of fluorophenylcarbene

Zhifeng Lu, Robert A. Moss, Ralf Warmuth, Karsten Krogh-Jespersen

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Laser flash photolysis of fluorophenyldiazirine incarcerated in hemicarcerand 2 affords incarcerated fluorophenylcarbene [23], which forms a metastable, innermolecular π-complex with aryl moieties of 2. This carbene complex can be observed spectroscopically. Extensive computational studies provide insights into the structure, spectroscopy, energetics, and kinetics of the 23 carbene complex.

Original languageEnglish (US)
Pages (from-to)13799-13803
Number of pages5
JournalJournal of Physical Chemistry A
Volume115
Issue number47
DOIs
StatePublished - Dec 1 2011

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Transient innermolecular carbene-hemicarcerand complex of fluorophenylcarbene'. Together they form a unique fingerprint.

Cite this