Two blue-light excitable yellow-emitting LMOF phosphors constructed by triangular tri(4-pyridylphenyl)amine

Fangming Wang; Zeyu Zhou; Wei Liu; Lei Zhou; Lizhuang Chen; Jing Li

doi:10.1039/c6dt03883b

Two blue-light excitable yellow-emitting LMOF phosphors constructed by triangular tri(4-pyridylphenyl)amine

Fangming Wang, Zeyu Zhou, Wei Liu, Lei Zhou, Lizhuang Chen, Jing Li

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Two luminescent metal-organic-frameworks (LMOFs) constructed by a molecular chromophore [tri(4-pyridylphenyl)amine] (tppa) were synthesized by solvothermal reactions and characterized by single crystal and powder X-ray diffraction, thermogravimetric analysis, optical diffuse reflection, photoluminescence spectroscopy, and internal quantum yield measurements. Both compound 1 [Zn(tppa)(ndc)·(DMF)₄] and compound 2 [Zn₄(tppa)₂(sdc)₃(NO₃)₂·(DMF)₄·(ACN)₂] (ndc = 2,6-naphthalenedicarboxylic acid, sdc = (E)-4,4′-(ethene-1,2-diyl)dibenzoic acid, DMF = dimethylformamide, ACN = acetonitrile) exhibit intense yellow emission under blue light (455 nm) excitation. The Commission International de I'Eclairage (CIE) coordinates of 1 (0.42, 0.53) and 2 (0.42, 0.54) are close to that of YAG:Ce³⁺ (0.41, 0.55) (λ_ex = 455 nm). The two phosphor materials show promise for use in phosphor-converted white LEDs (PC-WLEDs).

Original language	English (US)
Pages (from-to)	956-961
Number of pages	6
Journal	Dalton Transactions
Volume	46
Issue number	3
DOIs	https://doi.org/10.1039/c6dt03883b
State	Published - 2017

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

Access to Document

10.1039/c6dt03883b

Cite this

@article{7d559dd9cb67431f8a1512e4b7010ebc,

title = "Two blue-light excitable yellow-emitting LMOF phosphors constructed by triangular tri(4-pyridylphenyl)amine",

abstract = "Two luminescent metal-organic-frameworks (LMOFs) constructed by a molecular chromophore [tri(4-pyridylphenyl)amine] (tppa) were synthesized by solvothermal reactions and characterized by single crystal and powder X-ray diffraction, thermogravimetric analysis, optical diffuse reflection, photoluminescence spectroscopy, and internal quantum yield measurements. Both compound 1 [Zn(tppa)(ndc)·(DMF)4] and compound 2 [Zn4(tppa)2(sdc)3(NO3)2·(DMF)4·(ACN)2] (ndc = 2,6-naphthalenedicarboxylic acid, sdc = (E)-4,4′-(ethene-1,2-diyl)dibenzoic acid, DMF = dimethylformamide, ACN = acetonitrile) exhibit intense yellow emission under blue light (455 nm) excitation. The Commission International de I'Eclairage (CIE) coordinates of 1 (0.42, 0.53) and 2 (0.42, 0.54) are close to that of YAG:Ce3+ (0.41, 0.55) (λex = 455 nm). The two phosphor materials show promise for use in phosphor-converted white LEDs (PC-WLEDs).",

author = "Fangming Wang and Zeyu Zhou and Wei Liu and Lei Zhou and Lizhuang Chen and Jing Li",

note = "Funding Information: The RU team acknowledges the support from the National Science Foundation of USA (Grant No. DMR-1507210). The JUST team would like to thank the support from the National Natural Science Foundation of China (Grant No. 21671084). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6dt03883b",

language = "English (US)",

volume = "46",

pages = "956--961",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "3",

}

TY - JOUR

T1 - Two blue-light excitable yellow-emitting LMOF phosphors constructed by triangular tri(4-pyridylphenyl)amine

AU - Wang, Fangming

AU - Zhou, Zeyu

AU - Liu, Wei

AU - Zhou, Lei

AU - Chen, Lizhuang

AU - Li, Jing

N1 - Funding Information: The RU team acknowledges the support from the National Science Foundation of USA (Grant No. DMR-1507210). The JUST team would like to thank the support from the National Natural Science Foundation of China (Grant No. 21671084). Publisher Copyright: © The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - Two luminescent metal-organic-frameworks (LMOFs) constructed by a molecular chromophore [tri(4-pyridylphenyl)amine] (tppa) were synthesized by solvothermal reactions and characterized by single crystal and powder X-ray diffraction, thermogravimetric analysis, optical diffuse reflection, photoluminescence spectroscopy, and internal quantum yield measurements. Both compound 1 [Zn(tppa)(ndc)·(DMF)4] and compound 2 [Zn4(tppa)2(sdc)3(NO3)2·(DMF)4·(ACN)2] (ndc = 2,6-naphthalenedicarboxylic acid, sdc = (E)-4,4′-(ethene-1,2-diyl)dibenzoic acid, DMF = dimethylformamide, ACN = acetonitrile) exhibit intense yellow emission under blue light (455 nm) excitation. The Commission International de I'Eclairage (CIE) coordinates of 1 (0.42, 0.53) and 2 (0.42, 0.54) are close to that of YAG:Ce3+ (0.41, 0.55) (λex = 455 nm). The two phosphor materials show promise for use in phosphor-converted white LEDs (PC-WLEDs).

AB - Two luminescent metal-organic-frameworks (LMOFs) constructed by a molecular chromophore [tri(4-pyridylphenyl)amine] (tppa) were synthesized by solvothermal reactions and characterized by single crystal and powder X-ray diffraction, thermogravimetric analysis, optical diffuse reflection, photoluminescence spectroscopy, and internal quantum yield measurements. Both compound 1 [Zn(tppa)(ndc)·(DMF)4] and compound 2 [Zn4(tppa)2(sdc)3(NO3)2·(DMF)4·(ACN)2] (ndc = 2,6-naphthalenedicarboxylic acid, sdc = (E)-4,4′-(ethene-1,2-diyl)dibenzoic acid, DMF = dimethylformamide, ACN = acetonitrile) exhibit intense yellow emission under blue light (455 nm) excitation. The Commission International de I'Eclairage (CIE) coordinates of 1 (0.42, 0.53) and 2 (0.42, 0.54) are close to that of YAG:Ce3+ (0.41, 0.55) (λex = 455 nm). The two phosphor materials show promise for use in phosphor-converted white LEDs (PC-WLEDs).

UR - http://www.scopus.com/inward/record.url?scp=85010390736&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85010390736&partnerID=8YFLogxK

U2 - 10.1039/c6dt03883b

DO - 10.1039/c6dt03883b

M3 - Article

C2 - 28009865

AN - SCOPUS:85010390736

SN - 1477-9226

VL - 46

SP - 956

EP - 961

JO - Dalton Transactions

JF - Dalton Transactions

IS - 3

ER -

Two blue-light excitable yellow-emitting LMOF phosphors constructed by triangular tri(4-pyridylphenyl)amine

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this