Valence electron delocalization in polynuclear iron-sulfur clusters

L. Noodleman; D. A. Case; J. M. Mouesca; B. Lamotte

doi:10.1007/s007750050039

Valence electron delocalization in polynuclear iron-sulfur clusters

L. Noodleman, D. A. Case, J. M. Mouesca, B. Lamotte

Research output: Contribution to journal › Review article › peer-review

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Abstract

This commentary assesses the evidence for valence electron delocalization in dinuclear and polynuclear iron-sulfur clusters. We outline a simple Hamiltonian model that contains the important physical interactions and briefly review the experimental and computational tools that can be used to distinguish between valence electron delocalization and electron trapping and to assess likely magnitudes of resonance interactions.

Original language	English (US)
Pages (from-to)	177-182
Number of pages	6
Journal	Journal of Biological Inorganic Chemistry
Volume	1
Issue number	2
DOIs	https://doi.org/10.1007/s007750050039
State	Published - Apr 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Inorganic Chemistry

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10.1007/s007750050039

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title = "Valence electron delocalization in polynuclear iron-sulfur clusters",

abstract = "This commentary assesses the evidence for valence electron delocalization in dinuclear and polynuclear iron-sulfur clusters. We outline a simple Hamiltonian model that contains the important physical interactions and briefly review the experimental and computational tools that can be used to distinguish between valence electron delocalization and electron trapping and to assess likely magnitudes of resonance interactions.",

author = "L. Noodleman and Case, {D. A.} and Mouesca, {J. M.} and B. Lamotte",

year = "1996",

month = apr,

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T1 - Valence electron delocalization in polynuclear iron-sulfur clusters

AU - Noodleman, L.

AU - Case, D. A.

AU - Mouesca, J. M.

AU - Lamotte, B.

PY - 1996/4

Y1 - 1996/4

N2 - This commentary assesses the evidence for valence electron delocalization in dinuclear and polynuclear iron-sulfur clusters. We outline a simple Hamiltonian model that contains the important physical interactions and briefly review the experimental and computational tools that can be used to distinguish between valence electron delocalization and electron trapping and to assess likely magnitudes of resonance interactions.

AB - This commentary assesses the evidence for valence electron delocalization in dinuclear and polynuclear iron-sulfur clusters. We outline a simple Hamiltonian model that contains the important physical interactions and briefly review the experimental and computational tools that can be used to distinguish between valence electron delocalization and electron trapping and to assess likely magnitudes of resonance interactions.

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DO - 10.1007/s007750050039

M3 - Review article

AN - SCOPUS:0001330455

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JO - Journal of Biological Inorganic Chemistry

JF - Journal of Biological Inorganic Chemistry

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Valence electron delocalization in polynuclear iron-sulfur clusters

Abstract

All Science Journal Classification (ASJC) codes

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