Van der Waals complexes of the bichromophore spirobifluorene

Niels A. van Dantzig; Piotr Piotrowiak; Donald H. Levy

doi:10.1016/0009-2614(94)00418-8

Van der Waals complexes of the bichromophore spirobifluorene

Niels A. van Dantzig, Piotr Piotrowiak, Donald H. Levy

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Van der Waals complexes of the bichromophore spirobifluorene with argon, nitrogen, water, methanol, and acetonitrile were studied in a supersonic jet. The 1:1 complexes have two origin transitions which are shifted to the red and to the blue of the bare bichromophore origin. These spectral shifts are discussed in terms of the dispersive interactions in a three-body cluster. Larger argon clusters are identified by broad features which are caused by the spectral overlap of many origin transition. A model of vibronic coupling is suggested to explain the broadened features in some of the spectra.

Original language	English (US)
Pages (from-to)	127-132
Number of pages	6
Journal	Chemical Physics Letters
Volume	223
Issue number	1-2
DOIs	https://doi.org/10.1016/0009-2614(94)00418-8
State	Published - Jun 10 1994
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(94)00418-8

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title = "Van der Waals complexes of the bichromophore spirobifluorene",

abstract = "Van der Waals complexes of the bichromophore spirobifluorene with argon, nitrogen, water, methanol, and acetonitrile were studied in a supersonic jet. The 1:1 complexes have two origin transitions which are shifted to the red and to the blue of the bare bichromophore origin. These spectral shifts are discussed in terms of the dispersive interactions in a three-body cluster. Larger argon clusters are identified by broad features which are caused by the spectral overlap of many origin transition. A model of vibronic coupling is suggested to explain the broadened features in some of the spectra.",

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T1 - Van der Waals complexes of the bichromophore spirobifluorene

AU - van Dantzig, Niels A.

AU - Piotrowiak, Piotr

AU - Levy, Donald H.

PY - 1994/6/10

Y1 - 1994/6/10

N2 - Van der Waals complexes of the bichromophore spirobifluorene with argon, nitrogen, water, methanol, and acetonitrile were studied in a supersonic jet. The 1:1 complexes have two origin transitions which are shifted to the red and to the blue of the bare bichromophore origin. These spectral shifts are discussed in terms of the dispersive interactions in a three-body cluster. Larger argon clusters are identified by broad features which are caused by the spectral overlap of many origin transition. A model of vibronic coupling is suggested to explain the broadened features in some of the spectra.

AB - Van der Waals complexes of the bichromophore spirobifluorene with argon, nitrogen, water, methanol, and acetonitrile were studied in a supersonic jet. The 1:1 complexes have two origin transitions which are shifted to the red and to the blue of the bare bichromophore origin. These spectral shifts are discussed in terms of the dispersive interactions in a three-body cluster. Larger argon clusters are identified by broad features which are caused by the spectral overlap of many origin transition. A model of vibronic coupling is suggested to explain the broadened features in some of the spectra.

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-2

ER -

Van der Waals complexes of the bichromophore spirobifluorene

Abstract

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