Volatile compounds formed from the interaction between organoselenium and sulfur compounds

Guor Jien Wei, Chi-Tang Ho

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Scopus citations

Abstract

Selenium is an element toxic in large quantities, but an essential trace metal for mammals, birds, and many bacteria. Selenium-containing food also contains sulfur, and the ratio of Se: S is over 1:1x104. Selenium can replace sulfur easily, and the interaction between selenium and sulfur occurs easily as well. In order to investigate the potential interaction of organoselenium and organosulfur compounds, a model reaction of selenomethionine, glucose and diallyl disulfide was performed, and volatile products generated were identified by GC/AED and GC/MS. Atomic emission detector is a powerful detector due to its high sensitivity, elemental selectivity, and the ability of multielement analysis. When coupled with GC, it is able to monitor the elemental composition of eluates directly with high elemental specificity, tolerate of non-ideal separation, the selectivity of plasma emission being able to overcome the interference from complex matrixes, and detect multi-element simultaneously for empirical and molecular formula determination.

Original languageEnglish (US)
Title of host publicationVolatile Sulfur Compounds in Food
PublisherAmerican Chemical Society
Pages259-266
Number of pages8
ISBN (Print)9780841226166
DOIs
Publication statusPublished - Jan 1 2011

Publication series

NameACS Symposium Series
Volume1068
ISSN (Print)0097-6156
ISSN (Electronic)1947-5918

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Wei, G. J., & Ho, C-T. (2011). Volatile compounds formed from the interaction between organoselenium and sulfur compounds. In Volatile Sulfur Compounds in Food (pp. 259-266). (ACS Symposium Series; Vol. 1068). American Chemical Society. https://doi.org/10.1021/bk-2011-1068.ch013