Zn(tbip) (H2tbip= 5-tert-butyl isophthalic acid): A highly stable guest-free microporous metal organic framework with unique gas separation capability

Long Pan; Brett Parker; Xiaoying Huang; David H. Olson; Jeong Yong Lee; Jing Li

doi:10.1021/ja057667b

Zn(tbip) (H₂tbip= 5-tert-butyl isophthalic acid): A highly stable guest-free microporous metal organic framework with unique gas separation capability

Long Pan, Brett Parker, Xiaoying Huang, David H. Olson, Jeong Yong Lee, Jing Li

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

450 Scopus citations

Abstract

A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 Å. It demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density (0.054 g/cm³ at 77 K and 1 atm).

Original language	English (US)
Pages (from-to)	4180-4181
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	13
DOIs	https://doi.org/10.1021/ja057667b
State	Published - Apr 5 2006

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja057667b

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title = "Zn(tbip) (H2tbip= 5-tert-butyl isophthalic acid): A highly stable guest-free microporous metal organic framework with unique gas separation capability",

abstract = "A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 {\AA}. It demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density (0.054 g/cm3 at 77 K and 1 atm).",

author = "Long Pan and Brett Parker and Xiaoying Huang and Olson, {David H.} and Lee, {Jeong Yong} and Jing Li",

year = "2006",

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doi = "10.1021/ja057667b",

language = "English (US)",

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T2 - A highly stable guest-free microporous metal organic framework with unique gas separation capability

AU - Pan, Long

AU - Parker, Brett

AU - Huang, Xiaoying

AU - Olson, David H.

AU - Lee, Jeong Yong

AU - Li, Jing

PY - 2006/4/5

Y1 - 2006/4/5

N2 - A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 Å. It demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density (0.054 g/cm3 at 77 K and 1 atm).

AB - A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 Å. It demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density (0.054 g/cm3 at 77 K and 1 atm).

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Zn(tbip) (H₂tbip= 5-tert-butyl isophthalic acid): A highly stable guest-free microporous metal organic framework with unique gas separation capability

Abstract

All Science Journal Classification (ASJC) codes

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